Login for students

Login for employees

Publication detail

Reactivity of Lead(II) Compounds with Pb-N Bond
Authors: Růžička Aleš | Císařová Ivana
Year: 2004
Type of publication: ostatní - přednáška nebo poster
Name of source: Sborník str. P1
Publisher name: University of Texas
Place:
Page from-to:
Titles:
Language Name Abstract Keywords
cze Reactivity of Lead(II) Compounds with Pb-N Bond Generally, we have been recognized growing interest in lead and organolead chemistry, in past few years, where the special field are the lead(II) compounds.2 We have prepared and structurally characterized two diferrent lead(II) compounds. Both compounds reveal significant Pb-N bonding connection. First of them is organolead compound A1 (Scheme 1) with C,N-chelating ligand. Second one is the complex amidolead compound B. We tested the reactivity of both A and B towards oxidation and subtitution (X2, HX, O2, ArX, M(CO)x, carbenes, etc.). Products of these reaction were identified, structurally characterized by XRD, multinuclear NMR, MS and EA, some of prepared compounds were reacted with another nucleophilic or reducing agents (alkali metals, H2O, etc). Organolead compounds, reactivity
eng Reactivity of Lead(II) Compounds with Pb-N Bond Generally, we have been recognized growing interest in lead and organolead chemistry, in past few years, where the special field are the lead(II) compounds.2 We have prepared and structurally characterized two diferrent lead(II) compounds. Both compounds reveal significant Pb-N bonding connection. First of them is organolead compound A1 (Scheme 1) with C,N-chelating ligand. Second one is the complex amidolead compound B. We tested the reactivity of both A and B towards oxidation and subtitution (X2, HX, O2, ArX, M(CO)x, carbenes, etc.). Products of these reaction were identified, structurally characterized by XRD, multinuclear NMR, MS and EA, some of prepared compounds were reacted with another nucleophilic or reducing agents (alkali metals, H2O, etc).

Departments

Other Parts

Map

en.mapy.cz

Services

Popular Links

© 2023 University of Pardubice, Studentská 95, 532 10 Pardubice 2
Phone: +420 466 036 111, 466 036 112, 466 036 113
Webmaster, RSS
Data box ID: f5vj9hu
Accessibility Statement
CC BY-NC-ND 4.0Creative CommonsAttributionNonCommercialNoDerivatives